This collection presents papers from a symposium on extraction of rare metals from primary and secondary materials and residues as well as rare extraction processing techniques used in metal production. Contributions cover the extraction of less common or minor metals including elements such as antimony, bismuth, barium, beryllium, boron, calcium, chromium, gallium, germanium, hafnium, indium, manganese, molybdenum, platinum group metals, rare earth metals, rhenium, scandium, selenium, sodium, strontium, tantalum, tellurium, and tungsten. Also covered are rare metals of low-tonnage sales compared to high-tonnage metals (iron, copper, nickel, lead, tin, zinc, or light metals such as aluminum, magnesium, or titanium and electronic metalloid silicon). The collection also covers bio-metallurgy, hydrometallurgy, and electrometallurgy while novel high-temperature processes such as microwave heating, solar-thermal reaction synthesis, and cold crucible synthesis of rare metals are also addressed.